New synthetic methodologies based on active transition metals

被引：37

作者：

Alonso, Francisco

Yust, Miguel ^{[1
,2
]}

机构：

[1] Univ Alicante, Fac Sci, Dept Organ Chem, Alicante 03080, Spain

[2] Univ Alicante, Inst Organ Synth, Alicante 03080, Spain

来源：

PURE AND APPLIED CHEMISTRY | 2008年 / 80卷 / 05期

关键词：

active metals; nickel; copper; iron; nanoparticles; reduction; alkylation of ketones with alcohols;

D O I：

10.1351/pac200880051005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Active transition metals, namely, nickel, copper and iron, have been prepared by the reduction of the corresponding chlorides with lithium and a catalytic amount of an arene. These metals, in the form of nanoparticles, have found application in the reduction of a wide variety of functional groups as well as in the alkylation of methyl ketones with primary alcohols.

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页码：1005 / 1012

页数：8

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