A novel chain-like polymer constructed from heteropolyanions covalently linked by lanthanide cations:: (C5H9NO2)2[La(H2O)7CrMo6H6O24]•11H2O (proline=C5H9NO2)

被引：44

作者：

An, HY ^{[1
]}

Lan, Y ^{[1
]}

Li, YG ^{[1
]}

Wang, E ^{[1
]}

Hao, N ^{[1
]}

Xiao, DR ^{[1
]}

Duan, LY ^{[1
]}

Xu, L ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 03期

基金：

中国国家自然科学基金;

关键词：

chain-like polymer; lanthanum ion; hexamolybdochromate; proline;

D O I：

10.1016/j.inoche.2003.12.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polymer (C5H9NO2)(2)[La(H2O)(7)CrMo6H6O24] - 11H(2)O (1), has been synthesized and structurally characterized. Compound 1 exhibits a novel one-dimensional (1-D) chain-like structure consisting of Anderson-type polyoxoanions hexamolybdochromate [CrMo6H6O24](3-) covalently linked by hydrated La3+ ions, furthermore pseudo-2-D layers can be formed owing to the strong (La)OH2...O hydrogen bonds among adjacent chains. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：356 / 358

页数：3

共 22 条

[1] Lanthanide complexes of polyoxometalates: Characterization by tungsten-183 and phosphorus-31 nuclear magnetic resonance spectroscopy [J].

Bartis, J ;

Sukal, S ;

Dankova, M ;

Kraft, E ;

Kronzon, R ;

Blumenstein, M ;

Francesconi, LC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (11) :1937-1944

[2] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[3] OXOPEROXO(CITRATO)VANADATES(V) AND DIOXO(CITRATO)VANADATES(V) - SYNTHESIS, SPECTRA, AND STRUCTURE OF A HYDROXYL OXYGEN BRIDGED DIMER, K2[VO(O2)(C6H6O7)]2.2H2O [J].

DJORDJEVIC, C ;

LEE, M ;

SINN, E .

INORGANIC CHEMISTRY, 1989, 28 (04) :719-723

[4] Hybrid organic-anorganic 1D and 2D frameworks with ε-Keggin polyoxomolybdates as building blocks [J].

Dolbecq, A ;

Mialane, P ;

Lisnard, L ;

Marrot, J ;

Sécheresse, F .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (12) :2914-2920

[5] Synthesis, properties and structural characterization of an intermolecular photosensitive complex:: (HGly-Gly)3PMo12O40•4H2O [J].

Han, ZB ;

Wang, EB ;

Luan, GY ;

Li, YG ;

Zhang, H ;

Duan, YB ;

Hu, CW ;

Hu, NH .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (04) :1169-1173

[6] HOMOGENEOUS CATALYSIS BY TRANSITION-METAL OXYGEN ANION CLUSTERS [J].

HILL, CL ;

PROSSERMCCARTHA, CM .

COORDINATION CHEMISTRY REVIEWS, 1995, 143 :407-455

[7] Introduction: Polyoxometalates - Multicomponent molecular vehicles to probe fundamental issues and practical problems [J].

Hill, CL .

CHEMICAL REVIEWS, 1998, 98 (01) :1-2

[8] Novel two-dimensional sodium molybdenum phosphates containing {M(enMe)2}2+ bridging groups (M = Ni, Cu;: enMe=1,2-diaminopropane) [J].

Huang, RD ;

Liu, FC ;

Li, YG ;

Yuan, M ;

Wang, EB ;

De, GH ;

Hu, CW ;

Hu, NH ;

Jia, HQ .

INORGANICA CHIMICA ACTA, 2003, 349 :85-90

[9] Cation-directed structure changes in polyoxometalate chemistry. Equilibria between isomers of bis(9-tungstophosphatodioxouranate(VI)) complexes [J].

Kim, KC ;

Pope, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (37) :8512-8517

[10] THE STRUCTURE OF THE HEXAMOLYBDOPERIODATE ANION IN ITS POTASSIUM-SALT [J].

KONDO, H ;

KOBAYASHI, A ;

SASAKI, Y .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1980, 36 (MAR) :661-664

← 1 2 3 →