GaI: A versatile reagent for the synthetic chemist

被引：73

作者：

Baker, RJ ^{[1
]}

Jones, C ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Ctr Fundamental & Appl Main Grp Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

DALTON TRANSACTIONS | 2005年 / 08期

关键词：

D O I：

10.1039/b501310k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current renaissance in main group chemistry has been fuelled by the remarkable array of fundamentally interesting yet synthetically applicable low oxidation state p-block compounds that have appeared over the last decade. Their syntheses generally require the ready availability of low oxidation state element halide precursors. In the case of gallium this is provided by the simple to prepare reagent, "GaI", which since it was first reported in 1990, has been utilised in areas as varied as organic synthesis and gallium cluster construction. This article tracks the history of this extraordinary material and highlights its synthetic diversity; hopefully allowing the reader to envisage its application to aspects of their own research fields.

引用

页码：1341 / 1348

页数：8

共 71 条

[11] Analogies between the reactivities of an anionic gallium(I) heterocycle and N-heterocyclic carbenes toward metallocenes [J].

Baker, RJ ;

Jones, C ;

Platts, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (35) :10534-10535

[12]

Baker RJ, 2003, EUR J INORG CHEM, P2446

[13] Synthesis and structural characterization of thermally stable group 13 hydride complexes derived from a gallium(I) carbene analogue [J].

Baker, RJ ;

Jones, C ;

Kloth, M ;

Platts, JA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (23) :2660-2663

[14] The reaction of 'GaI' with a 1,3-diyne:: synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(III)) complex [J].

Baker, RJ ;

Jones, C .

CHEMICAL COMMUNICATIONS, 2003, (03) :390-391

[15] Synthesis and characterisation of the first carbene and diazabutadiene-indium(II) complexes [J].

Baker, RJ ;

Farley, RD ;

Jones, C ;

Kloth, M ;

Murphy, DM .

CHEMICAL COMMUNICATIONS, 2002, (11) :1196-1197

[16] The reactivity of diazabutadienes toward low oxidation state Group 13 iodides and the synthesis of a new gallium(I) carbene analogue [J].

Baker, RJ ;

Farley, RD ;

Jones, C ;

Kloth, M ;

Murphy, DM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (20) :3844-3850

[17]

BAKER RJ, IN PRESS COORD CHEM

[18]

BAKER RJ, IN PRESS CHEM EUR J

[19]

BAUNN NR, UNPUB ORGANOMETALLIC

[20] Synthesis and structural characterization of cyclopentadienyliron- and cyclopentadienylmolybdenum-gallium compounds [J].

Borovik, AS ;

Bott, SG ;

Barron, AR .

ORGANOMETALLICS, 1999, 18 (14) :2668-2676

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