Synthesis and characterisation of the first carbene and diazabutadiene-indium(II) complexes

被引：55

作者：

Baker, RJ ^{[1
]}

Farley, RD ^{[1
]}

Jones, C ^{[1
]}

Kloth, M ^{[1
]}

Murphy, DM ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 11期

关键词：

D O I：

10.1039/b202532a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of IMes [:CN( Mes) C2H2N(Mes), Mes = mesityl] and DAB [(ArN=CH)(2), Ar = C6H3Pr2i-2,6] with indium( I) halides have afforded the first carbene and diazabutadiene indium( II) complexes, [In2Br4(IMes)(2)] and [In2Cl2( DAB.)(2)], both of which have been crystallographically characterised.

引用

页码：1196 / 1197

页数：2

共 13 条

[1] Preparation, characterization, and reactivity of the stable indium trihydride complex [InH3{CN(Mes)C2H2N(Mes)}] [J].

Abernethy, CD ;

Cole, ML ;

Jones, C .

ORGANOMETALLICS, 2000, 19 (23) :4852-4857

[2] GALLIUM-CONTAINING 6-PI-ELECTRON RING-SYSTEMS [J].

BROWN, DS ;

DECKEN, A ;

COWLEY, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5421-5422

[3] Synthesis and characterisation of the first carbene-thallium complexes:: molecular structure of [TiCl3{CN(Mes)C2H2N(Mes)}], Mes = C6H2Me3-2,4,6 [J].

Cole, ML ;

Davies, AJ ;

Jones, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (17) :2451-2452

[4] PARAMAGNETIC BIS(1,4-DI-TERT-BUTYL-1,4-DIAZABUTADIENE) ADDUCTS OF LITHIUM, MAGNESIUM, AND ZINC [J].

GARDINER, MG ;

HANSON, GR ;

HENDERSON, MJ ;

LEE, FC ;

RASTON, CL .

INORGANIC CHEMISTRY, 1994, 33 (11) :2456-2461

[5] Reaction of indium metal with R3PI2 (R=Ph, Pr-i, Pr-n); structural characterisation of the novel 'subvalent' indium(II) complex In2I4(PPr3n)(2) which contains an In-In bond, the four- and five-coordinate indium(III) complex InI3(PPh3)(2)center dot InI3(PPh3), and the tetrahedral indium(III) complex InI3(PPr3i) [J].

Godfrey, SM ;

Kelly, KJ ;

Kramkowski, P ;

McAuliffe, CA ;

Pritchard, RG .

CHEMICAL COMMUNICATIONS, 1997, (11) :1001-1002

[6] Low valent aluminum and gallium compounds -: structural variety and coordination modes to transition metal fragments [J].

Linti, G ;

Schnöckel, H .

COORDINATION CHEMISTRY REVIEWS, 2000, 206 :285-319

[7] A carbene analogue with low-valent gallium as a heteroatom in a quasi-aromatic imidazolate anion [J].

Schmidt, ES ;

Jockisch, A ;

Schmidbaur, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9758-9759

[8] In further pursuit of the carbene analogy:: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I) [J].

Schmidt, ES ;

Schier, A ;

Schmidbaur, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (05) :505-507

[9] From AIX/GaX monohalide molecules to metalloid aluminum and gallium clusters [J].

Schnöckel, H ;

Schnepf, A .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 47, 2001, 47 :235-281

[10] On the electronic structure of main group diazadiene complexes, with boron, aluminium, gallium and indium, a density functional evaluation [J].

Schoeller, WW ;

Grigoleit, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (03) :405-409

← 1 2 →