Low valent aluminum and gallium compounds -: structural variety and coordination modes to transition metal fragments

被引:189
作者
Linti, G [1 ]
Schnöckel, H [1 ]
机构
[1] Univ Karlsruhe, TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
关键词
aluminum; gallium; transition metals; clusters; low valent;
D O I
10.1016/S0010-8545(00)00339-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The chemistry of low valent aluminum and gallium compounds is a very topical area of research. Accompanying the preparative challenge in synthesizing novel types of main group cluster compounds and transition metal complexes with aluminum and gallium ligands, an area of chemistry is being exploited, which requires new insight on the description of chemical bonds. Therefore, not only are routes to these compounds and their structures described here, but thoughts on the description of bonding are presented as well. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:285 / 319
页数:35
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