Low valent aluminum and gallium compounds -: structural variety and coordination modes to transition metal fragments

被引:189
作者
Linti, G [1 ]
Schnöckel, H [1 ]
机构
[1] Univ Karlsruhe, TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
关键词
aluminum; gallium; transition metals; clusters; low valent;
D O I
10.1016/S0010-8545(00)00339-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The chemistry of low valent aluminum and gallium compounds is a very topical area of research. Accompanying the preparative challenge in synthesizing novel types of main group cluster compounds and transition metal complexes with aluminum and gallium ligands, an area of chemistry is being exploited, which requires new insight on the description of chemical bonds. Therefore, not only are routes to these compounds and their structures described here, but thoughts on the description of bonding are presented as well. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:285 / 319
页数:35
相关论文
共 105 条
[31]  
KLINKHAMMER KW, 1997, ANGEW CHEM, V109, P2414
[32]   ELECTRONIC SHELL STRUCTURE AND ABUNDANCES OF SODIUM CLUSTERS [J].
KNIGHT, WD ;
CLEMENGER, K ;
DEHEER, WA ;
SAUNDERS, WA ;
CHOU, MY ;
COHEN, ML .
PHYSICAL REVIEW LETTERS, 1984, 52 (24) :2141-2143
[33]  
Köppe R, 2000, Z ANORG ALLG CHEM, V626, P1095
[34]   A monovalent gallium complex supported by tris(3,5-di-tert-butylpyrazolyl)hydroborato ligation: The syntheses and structures of [TpBu(2)(t)]Ga and its GaI3 adduct, [TpBu(2)(t)]Ga->GaI31 [J].
Kuchta, MC ;
Bonanno, JB ;
Parkin, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (44) :10914-10915
[35]   INTERMEDIATE BINARY CARBONYLS OF PALLADIUM PD(CO)N WHERE = 1-3 - PREPARATION, IDENTIFICATION, AND DIFFUSION KINETICS BY MATRIX ISOLATION INFRARED SPECTROSCOPY [J].
KUNDIG, EP ;
MOSKOVIT.M ;
OZIN, GA .
CANADIAN JOURNAL OF CHEMISTRY, 1972, 50 (22) :3587-&
[36]   Cyclogallanes and metalloaromaticity, synthesis and molecular structure of dipotassium tris((2,6-dimesityphenyl)cyclogallene), K-2[(Mes(2)C(6)H(3))Ga](3) (Mes=2,4,6-Me(3)C(6)H(2)): A structural and theoretical examination [J].
Li, XW ;
Xie, YM ;
Schreiner, PR ;
Gripper, KD ;
Critendon, RC ;
Campana, CF ;
Schaefer, HF ;
Robinson, GH .
ORGANOMETALLICS, 1996, 15 (18) :3798-3803
[37]   A METALLIC SYSTEM WITH AROMATIC CHARACTER - SYNTHESIS AND MOLECULAR-STRUCTURE OF NA-2[(MES(2)C(6)H(3))GA](3) (MES=2,4,6-ME(3)C(6)H(2)) - THE FIRST CYCLOGALLANE [J].
LI, XW ;
PENNINGTON, WT ;
ROBINSON, GH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (28) :7578-7579
[38]  
Linti G, 1998, CHEM-EUR J, V4, P942, DOI 10.1002/(SICI)1521-3765(19980515)4:5<942::AID-CHEM942>3.3.CO
[39]  
2-Z
[40]  
Linti G, 1998, ANGEW CHEM INT EDIT, V37, P2209, DOI 10.1002/(SICI)1521-3773(19980904)37:16<2209::AID-ANIE2209>3.0.CO