Low valent aluminum and gallium compounds -: structural variety and coordination modes to transition metal fragments

被引：189

作者：

Linti, G ^{[1
]}

Schnöckel, H ^{[1
]}

机构：

[1] Univ Karlsruhe, TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷

关键词：

aluminum; gallium; transition metals; clusters; low valent;

D O I：

10.1016/S0010-8545(00)00339-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemistry of low valent aluminum and gallium compounds is a very topical area of research. Accompanying the preparative challenge in synthesizing novel types of main group cluster compounds and transition metal complexes with aluminum and gallium ligands, an area of chemistry is being exploited, which requires new insight on the description of chemical bonds. Therefore, not only are routes to these compounds and their structures described here, but thoughts on the description of bonding are presented as well. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：285 / 319

页数：35

共 105 条

[81]

SIEGERT H, 1966, ANWENDUNGEN SCHWINGU

[82] Cyclopentadienyl derivatives of aluminum (I) [J].

Sitzmann, H ;

Lappert, MF ;

Dohmeier, C ;

Uffing, C ;

Schnockel, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 561 (1-2) :203-208

[83] How short is a -Ga Ga- triple bond? Synthesis and molecular structure of Na-2[Mes*2C6H3-Ga Ga-C(6)H(3)Mes*(2)] (Mes*=2,4,6-i-Pr3C6H2): The first gallyne [J].

Su, JR ;

Li, XW ;

Crittendon, RC ;

Robinson, GH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (23) :5471-5472

[84] Experimental confirmation of an iron-gallium multiple bond: Synthesis, structure, and bonding of a ferrogallyne [J].

Su, JR ;

Li, XW ;

Crittendon, RC ;

Campana, CF ;

Robinson, GH .

ORGANOMETALLICS, 1997, 16 (21) :4511-4513

[85] METASTABLE ALCL AS A SOLID AND IN SOLUTION [J].

TACKE, M ;

SCHNOCKEL, H .

INORGANIC CHEMISTRY, 1989, 28 (14) :2895-2896

[86] Pd59(CO)32(PMe3)21:: A nanosized metal cluster containing a trigonal D3 Pd59 core with 11 interior palladium atoms [J].

Tran, NT ;

Kawano, M ;

Powell, DR ;

Dahl, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) :10986-10987

[87] Synthesis, structure, and bonding of a polyhedral A12Co2 cluster [J].

Uffing, C ;

Ecker, A ;

Koppe, R ;

Schnockel, H .

ORGANOMETALLICS, 1998, 17 (11) :2373-2375

[88]

Üffing C, 1998, ANGEW CHEM INT EDIT, V37, P2397, DOI 10.1002/(SICI)1521-3773(19980918)37:17<2397::AID-ANIE2397>3.0.CO

[89]

2-K

[90]

UFFING C, 1998, ANGEW CHEM, V110, P2488

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