Synthesis, structure, and bonding of a polyhedral A12Co2 cluster

被引：46

作者：

Uffing, C ^{[1
]}

Ecker, A ^{[1
]}

Koppe, R ^{[1
]}

Schnockel, H ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Inorgan Chem, D-76128 Karlsruhe, Germany

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 11期

关键词：

D O I：

10.1021/om9710576

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(mu-(pentamethylcyclopentadienyl)aluminio)-hexacarbonyldicobalt, (mu-Cp*Al)(2)Co-2(CO)(6), is formed in the reaction between AlCp* (Cp* = C5Me5) and Co-2(CO)(8) in toluene. The bonding description as a polyhedral Al2Co2 cluster in, which AlCp* has completely lost its originally carbene-like character is based on X-ray data as well as on DFT calculations.

引用

页码：2373 / 2375

页数：3

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