Experimental confirmation of an iron-gallium multiple bond: Synthesis, structure, and bonding of a ferrogallyne

被引：124

作者：

Su, JR

Li, XW

Crittendon, RC

Campana, CF

Robinson, GH

机构：

[1] UNIV GEORGIA, DEPT CHEM, ATHENS, GA 30602 USA

[2] SIEMENS ENERGY & AUTOMAT INC, ANALYT XRAY DIV, MADISON, WI 53719 USA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 21期

关键词：

D O I：

10.1021/om970530c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of disodium tetracarbonylferrate, Na-2[Fe(CO)(4)], with [2, 6-bis(2,4, 6-triisopropylphenyl)-phenyl]gallium dichloride, (Mes*2C6H3)GaCl2 (Mes* = 2,4,6-triisopropylphenyl), affords tetracarbonyliron [2,6-bis(2,4,6-triisopropylphenyl)phenyl]gallyne (CO)(4)Fe drop Ga(C(6)H(3)Mes*(2)), as anaerobically stable yellow prism crystals. The title compound offers evidence in support of an iron-gallium triple bond-the first ferrogallyne.

引用

页码：4511 / 4513

页数：3

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