In further pursuit of the carbene analogy:: preparation and crystal structure of (N,N,N′,N′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)

被引：49

作者：

Schmidt, ES ^{[1
]}

Schier, A ^{[1
]}

Schmidbaur, H ^{[1
]}

机构：

[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 05期

关键词：

D O I：

10.1039/b101016f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of cis-ethene-1,2-di(tert-butylamido)gallium(III) chloride with metallic potassium in the presence of N,N,N',N'-tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations eta (5)-coordinated to the pseudo-carbene ring system of one monomer and eta (1)-bonded to the gallium atom of the other.

引用

页码：505 / 507

页数：3

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