Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis

被引：42

作者：

Boersma, Arnold J. ^{[1
]}

de Bruin, Bas ^{[2
]}

Feringa, Ben L. ^{[1
]}

Roelfes, Gerard ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 18期

关键词：

ARTIFICIAL TRANSFER HYDROGENASES; TERNARY COPPER(II) COMPLEXES; DIELS-ALDER REACTION; DESIGN;

D O I：

10.1039/c2cc17350f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

DNA-based catalysis can be used to control the enantioselectivity of copper-catalysed Diels-Alder and Friedel-Crafts reactions to produce either enantiomer of the product by changing the denticity of the ligand coordinated to the Cu(II) ion, even though the DNA adopts a right handed helical conformation only.

引用

页码：2394 / 2396

页数：3

共 22 条

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