Calix[n]arene sulfonic acids bearing pendant aliphatic chains as recyclable surfactant-type Bronsted acid catalysts for allylic alkylation with allyl alcohols in water

被引：104

作者：

Liu, Yu-Liang ^{[1
]}

Liu, Li ^{[1
]}

Wang, Yi-Lin ^{[1
]}

Han, Yu-Chun ^{[1
]}

Wang, Dong ^{[1
]}

Chen, Yong-Jun ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Biol Chem Lab, Inst Chem, Beijing 100080, Peoples R China

来源：

GREEN CHEMISTRY | 2008年 / 10卷 / 06期

关键词：

D O I：

10.1039/b719278a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calix[n]arene sulfonic acids bearing pendant aliphatic chains were developed as surfactant-type Bronsted acid catalysts for allylic alkylation with allyl alcohols in water. The allylic alkylation products of aromatic compounds were obtained in 60-94% yields. The water-solution of the surfactant-type catalyst was recovered by means of simple extraction of water-insoluble products and centrifiguation, which can be reused in the next cycle directly. After recycling seven times, the catalytic activity for the aqueous reaction still remained at a high level (92-96% yields).

引用

页码：635 / 640

页数：6

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