Submicrometer-sized vaterite tubes formed through nanobubble-templated crystal growth

被引:41
作者
Fan, YW [1 ]
Wang, RZ [1 ]
机构
[1] Univ British Columbia, Dept Mat Engn, Vancouver, BC V6T 1Z4, Canada
关键词
D O I
10.1002/adma.200500755
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrolytic deposition is used to prepare submicrometer-sized vaterite (CaCO3) tubes (see Figure) in the absence of organic molecules, the presence of which was previously thought to be necessary for the growth of calcium carbonate crystals in complex morphologies. The mechanism of formation is shown experimentally to be hydrogen-nanobubble-templated crystal growth.
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页码:2384 / +
页数:6
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共 40 条
[11]   Nucleation-growth processes of scale crystallization under electrochemical reaction investigated by in situ microscopy [J].
Devos, O ;
Gabrielli, C ;
Tribollet, B .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (10) :C73-C76
[12]   Electrochemical synthesis of calcium carbonate coatings on stainless steel substrates [J].
Dinamani, M ;
Kamath, PV ;
Seshadri, R .
MATERIALS RESEARCH BULLETIN, 2002, 37 (04) :661-669
[13]   Control of aragonite or calcite polymorphism by mollusk shell macromolecules [J].
Falini, G ;
Albeck, S ;
Weiner, S ;
Addadi, L .
SCIENCE, 1996, 271 (5245) :67-69
[14]   Influence on the formation of aragonite or vaterite by otolith macromolecules [J].
Falini, G ;
Fermani, S ;
Vanzo, S ;
Miletic, M ;
Zaffino, G .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, Wiley-VCH Verlag (01) :162-167
[15]   A composite coating by electrolysis-induced collagen self-assembly and calcium phosphate mineralization [J].
Fan, YW ;
Duan, K ;
Wang, RZ .
BIOMATERIALS, 2005, 26 (14) :1623-1632
[16]   Study of the electrochemical deposition of CaCO3 by in situ Raman spectroscopy -: I.: Influence of the substrate [J].
Gabrielli, C ;
Jaouhari, R ;
Joiret, S ;
Maurin, G ;
Rousseau, P .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (07) :C478-C484
[17]   Calcium carbonate films and helices grown in solutions of poly(aspartate) [J].
Gower, LA ;
Tirrell, DA .
JOURNAL OF CRYSTAL GROWTH, 1998, 191 (1-2) :153-160
[18]   Naturally precipitating vaterite (μ-CaCO3) spheres:: Unusual carbonates formed in an extreme environment [J].
Grasby, SE .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2003, 67 (09) :1659-1666
[19]   ORIENTED CRYSTALLIZATION OF CACO3 UNDER COMPRESSED MONOLAYERS .2. MORPHOLOGY, STRUCTURE AND GROWTH OF IMMATURE CRYSTALS [J].
HEYWOOD, BR ;
RAJAM, S ;
MANN, S .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (05) :735-743
[20]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58