Review on green chemistry -: Suzuki cross coupling in aqueous media

被引:115
作者
Franzén, R
Xu, YJ
机构
[1] Tampere Univ Technol, Inst Mat Chem, FIN-33720 Tampere, Finland
[2] Shenyang Pharmaceut Univ, Sch Pharmaceut Engn, Shenyang 110016, Peoples R China
关键词
Suzuki reaction; green chemistry; metal-catalyzed cross; coupling reactions; aqueous synthesis media;
D O I
10.1139/V05-048
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Suzuki cross-coupling reaction is a very efficient, reliable, and environmentally friendly method for the introduction of novel carbon-carbon bonds into molecules. This review summarizes recent advances in the use of the reaction in aqueous media with a focus on different types of ligands and the ligandless protocols currently in use. Several synthetic targets for the reaction have been mentioned. The work summarizes recent results from studies on asymmetric Suzuki reactions performed in organic - aqueous mixed solvents.
引用
收藏
页码:266 / 272
页数:7
相关论文
共 68 条
[51]   Catalytic cross-coupling reactions in biaryl synthesis [J].
Stanforth, SP .
TETRAHEDRON, 1998, 54 (3-4) :263-303
[52]   The palladium(0) Suzuki cross-coupling reaction as the key step in the synthesis of aporphinoids [J].
Suau, R ;
Rico, R ;
Nájera, F ;
Ortiz-López, FJ ;
López-Romero, JM ;
Moreno-Mañas, M ;
Roglans, A .
TETRAHEDRON, 2004, 60 (27) :5725-5735
[53]  
Sundberg R.J., 1996, INDOLES
[54]   Palladium charcoal-catalyzed Suzuki-Miyaura coupling to obtain arylpyridines and arylquinolines [J].
Tagata, T ;
Nishida, M .
JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (24) :9412-9415
[55]  
Tsuji J., 2002, Transition Metal Reagents and Catalysts: Innovations in Organic Synthesis
[56]   Total synthesis of gymnocin-A [J].
Tsukano, C ;
Sasaki, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) :14294-14295
[57]   On a new formation-manner of diphenyl-amine-derivatives. [Preliminary announcement.] [J].
Ullmann, F .
BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1903, 36 :2382-2384
[58]  
Vankelekom I. F. J., 2000, CHIRAL CATALYST IMMO
[59]   Chitosan-supported palladium catalyst. 1. Synthesis procedure [J].
Vincent, T ;
Guibal, E .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (21) :5158-5164
[60]   IN AQUA SYNTHESIS OF WATER-SOLUBLE POLY(PARA-PHENYLENE) DERIVATIVES [J].
WALLOW, TI ;
NOVAK, BM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7411-7412