Room-temperature catalytic hydrodefluorination of C(sp3)-F bonds

被引：277

作者：

Scott, VJ ^{[1
]}

Çelenligil-Çetin, R ^{[1
]}

Ozerov, OV ^{[1
]}

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 09期

关键词：

D O I：

10.1021/ja0426138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Room-temperature catalytic hydrodefluorination of the strong C(sp3)-F bonds in benzotrifluorides and fluoropentane is catalyzed by Et3Si[B(C6F5)4] and uses Et3SiH as the source of H. Ar-CF3 compounds are converted to Ar-CH3 and fluropentane to pentane. The reaction is thought to proceed via abstraction of F- by Et3Si[B(C6F5)4], and the substituent effects are consistent with this hypothesis. Copyright © 2005 American Chemical Society.

引用

页码：2852 / 2853

页数：2

共 44 条

[41] The chemistry of volatile waste from silicon wafer processing [J].