Stimuli-responsive gels from reversible coordination polymers

被引:198
作者
Kim, HJ
Lee, JH
Lee, M
机构
[1] Yonsei Univ, Ctr Supramol Nanoassembly, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
关键词
coordination modes; host-guest systems; ion exchange; sol-gel processes; supramolecular chemistry;
D O I
10.1002/anie.200501270
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Sol-gel switching is triggered by counter-anion guest exchange. The secondary structures of reversible coordination polymers can interconvert from a folded helical conformation (gel) into an unfolded zigzag conformation (sol) and back again in aqueous media (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5810 / 5814
页数:5
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