Characterization of spray pyrolysed indium sulfide thin films

被引:130
作者
John, TT [1 ]
Bini, S
Kashiwaba, Y
Abe, T
Yasuhiro, Y
Kartha, CS
Vijayakumar, KP
机构
[1] Cochin Univ Sci & Technol, Dept Phys, Cochin 682022, Kerala, India
[2] Iwate Univ, Dept Elect & Elect Engn, Morioka, Iwate 0208551, Japan
[3] Sendai Coll Engn, Sendai, Miyagi 9893128, Japan
关键词
D O I
10.1088/0268-1242/18/6/317
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Indium sulfide thin films have been prepared using the chemical spray pyrolysis technique. Samples with different substrate temperatures and indium-to-sulfur (In/S) ratios have been prepared and characterized using x-ray diffraction (XRD), x-ray photoelectron spectroscopy, photosensitivity measurements and optical absorption studies. XRD studies have revealed that the samples are beta-In2S3. The optical bandgap has been found to decrease from 2.81 to 2.64 eV with the In/S ratio varying from 2/1 to 2/8. The photoresponse of the samples can be improved by changing either the In/S ratio in the solution or the substrate temperature. From this study we observe that, in terms of crystallinity, bandgap and photoresponse, the sample with the In/S ratio of 1.2/8 is very suitable for any photovoltaic application.
引用
收藏
页码:491 / 500
页数:10
相关论文
共 23 条
[21]   Novel precursors for the growth of α-In2S3:trisdialkyldithiocarbamates of indium [J].
O'Brien, P ;
Otway, DJ ;
Walsh, JR .
THIN SOLID FILMS, 1998, 315 (1-2) :57-61
[22]   ON CONDUCTION MECHANISM IN SINGLE CRYSTAL BETA-INDIUM SULFIDE IN2S3 [J].
REHWALD, W ;
HARBEKE, G .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1965, 26 (08) :1309-&
[23]  
Yu SH, 1999, J AM CERAM SOC, V82, P457