Well-controlled synthesis of block copolythiophenes

被引：112

作者：

Ohshimizu, Kaoru ^{[1
]}

Ueda, Mitsuru ^{[1
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

来源：

MACROMOLECULES | 2008年 / 41卷 / 14期

关键词：

D O I：

10.1021/ma8005894

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Well-controlled rod-rod block copolymers, poly (3-hexylthiophene)-b-poly (3-phenoxymethylthiophene)s, were Successfully prepared by nickel-catalyzed coupling polymerization of 2-bromo-3-hexyl-5-iodothiophene followed by that of 2,5-dibromo-3-phenoxymethylthiophene. The homopolymerization of 2,5-dibromo-3-phenoxymethylthiophene was investigated in detail to determine the polymerization conditions. The structure of block copolymers was confirmed by FT-IR and H-1 NMR spectroscopies, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), ultraviolet-visible (UV-vis), and fluorescence spectroscopies. The thin film formed on a silicon wafer and annealed at 40 degrees C for 3 days was analyzed using atomic force microscopy (AFM), and the results indicated the existence of phase separation.

引用

页码：5289 / 5294

页数：6

共 27 条

[11]

Myongsoo L, 2001, CHEM REV, V101, P3869

[12] Synthesis of Poly(N-fluoroalkyl benzamide) with controlled molecular weight and polydispersity index [J].