Fabrication of gadolinium biphthalocyanine nano/microwires by electrophoretic deposition

被引：15

作者：

Chen, HZ ^{[1
]}

Cao, L ^{[1
]}

Zhou, HB ^{[1
]}

Rong, Y ^{[1
]}

Wang, M ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Polymer Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF CRYSTAL GROWTH | 2005年 / 281卷 / 2-4期

基金：

中国国家自然科学基金;

关键词：

optical properties; electrochemical growth; nanomaterials; organic compounds;

D O I：

10.1016/j.jcrysgro.2005.04.071

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The gadolinium biphthalocyanine (GdPc2) nano/microwires were fabricated by the electrophoretic deposition (EPD) method from a mixed solution of chloroform and trifluoroacetic acid containing the protonated GdPc2. The morphologies of the nano/microwires were manipulated by deposition time, concentration in the mixed solvents, and applied voltage, and were characterized by AFM and SEM. By increasing the deposition time, four morphologies from nanoparticles, nanowire, to microrods and leaf-like microcrystallites were grown. Scissor-like Y-junction microwire were formed by tuning the applied voltage during the deposition. The EPD mechanism was studied by spectroscopy measurement. The possible molecular stacking of GdPc2 in the nano/microwires was as well investigated via X-ray diffraction. The deposited films of GdPc, showed interesting photoresponse in the near infrared (NIR) region, indicating the possibility of fabricating NIR photodetectors. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：530 / 537

页数：8

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