The half-sandwich hydride and 16-electron complexes of rhodium and iridium containing (1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine:: Relevant to the asymmetric transfer hydrogenation

被引：99

作者：

Mashima, K ^{[1
]}

Abe, T ^{[1
]}

Tani, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 12期

关键词：

D O I：

10.1246/cl.1998.1201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We prepared the half-sandwich hydride and 16-electron complexes of rhodium and iridium bearing an anion of (1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethylediamine: for the iridium catalyst system, a 16-electron complex 2b and an 18-electron, hydride complex 3b were synthesized, while only a 16-electron complex 2a was detected for the rhodium catalyst.

引用

页码：1201 / 1202

页数：2

共 21 条

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