Asymmetric transfer hydrogenation catalyzed by diamine-iridium(I) complexes

被引：54

作者：

Inoue, S ^{[1
]}

Nomura, K ^{[1
]}

Hashiguchi, S ^{[1
]}

Noyori, R ^{[1
]}

Izawa, Y ^{[1
]}

机构：

[1] RES DEV CORP JAPAN, ERATO, MOL CATALYSIS PROJECT, TOYOTA, AICHI 47003, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 09期

关键词：

D O I：

10.1246/cl.1997.957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric transfer hydrogenation of a range of aromatic ketones in 2-propanol was carried out by using the iridium(I) complexes, prepared from [IrCl(cod)](2) and a variety of chiral diamine ligands derived from alpha-amino acids. Good catalytic activity and enantioselectivity were observed in the presence of KOH at room temperature.

引用

页码：957 / 958

页数：2

共 15 条

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