A magnesium-lithium heterometallic coordination network

被引:10
作者
Calderone, Paul J. [1 ]
Banerjee, Debasis [1 ]
Borkowski, Lauren A. [2 ]
Parise, John B. [1 ,2 ,3 ,4 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[2] SUNY Stony Brook, Inst Mineral Phys, Stony Brook, NY 11794 USA
[3] SUNY Stony Brook, Dept Geosci Earth & Space Sci Bldg, Stony Brook, NY 11794 USA
[4] Brookhaven Natl Lab, Light Source Div, Upton, NY 11973 USA
基金
美国国家科学基金会;
关键词
Metal-organic frameworks; Heterometallic coordination polymers; S-block metals; Lightweight metal centers; METAL-ORGANIC FRAMEWORK; STRUCTURAL-CHARACTERIZATION; GAS-ADSORPTION; POLYMER; SUBSTITUTION;
D O I
10.1016/j.inoche.2011.02.025
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A three-dimensional magnesium-lithium coordination network, Mg(2)Li(BTC) (HBTC)(DMF)(2), (1) (BTC = 1,3,5-benzenetricarboxylate; DMF=N,N-dimethylformamide), the first example of a mixed-metal Mg-Li coordination network, is synthesized using solvothermal techniques. Structural characterization was completed using single crystal x-ray techniques while thermal properties and surface area measurements were conducted by thermogravimetric and BET analysis, respectively. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:741 / 744
页数:4
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