Microflow photo-radical chlorination of cycloalkanes

被引：44

作者：

Matsubara, Hiroshi ^{[1
]}

Hino, Yoshiko ^{[1
]}

Tokizane, Masashi ^{[1
]}

Ryu, Ilhyong ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Osaka 5998531, Japan

来源：

CHEMICAL ENGINEERING JOURNAL | 2011年 / 167卷 / 2-3期

关键词：

Microreactor; Radical chlonnation; Sulfuryl chloride; Molecular chlorine; Photoreaction; CONTINUOUS-FLOW SYNTHESIS; SULFURYL CHLORIDE CHLORINATION; IONIC LIQUID; ALKANES; MICROREACTORS; PHOTOCYCLOADDITION; FLUORINATION; CHEMISTRY; HYDROGEN; SYSTEM;

D O I：

10.1016/j.cej.2010.08.086

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Photo-initiated radical chlorination of cycloalkanes was investigated using microflow reactors. Under natural light, microflow chlorination of cyclohexane with molecular chlorine proceeded well to give chlorocyclohexane with high selectivity for single-chlorination. Single-chlorination reaction of cycloalkanes with sulfuryl chloride can also be successfully carried out using a microflow reactor under irradiation using a 15W black light. (C) 2010 Elsevier BM. All rights reserved.

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页码：567 / 571

页数：5

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