Phosphine-catalyzed dimerization of activated alkenes under ambient and high pressure conditions

被引：46

作者：

Jenner, G ^{[1
]}

机构：

[1] Univ Strasbourg 1, Fac Chim, Lab Piezochim Organ, UMR 7509, F-67008 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 17期

关键词：

dimerization; Morita-Baylis-Hillman reaction; acrylic compounds; phosphines; pressure;

D O I：

10.1016/S0040-4039(00)00346-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acrylic compounds dimerize under Morita-Baylis-Hilrman conditions in the presence of soluble phosphines. Dimerization of P-substituted analogs may require high pressures. The process is selective and high yielding and affords densely functionalized products. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3091 / 3094

页数：4

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