Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3- by mild, non-aqueous reductive aggregation

被引：24

作者：

Bakri, Ridla ^{[1
]}

Booth, Andrew ^{[1
]}

Harle, Gavin ^{[1
]}

Middleton, Paul S. ^{[1
]}

Wills, Corinne ^{[1
]}

Clegg, William ^{[1
]}

Harrington, Ross W. ^{[1
]}

Errington, R. John ^{[1
]}

机构：

[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

BOND-VALENCE PARAMETERS; RAY CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESES; BUILDING-BLOCKS; FRAMEWORKS; POLYANION; CLUSTERS; MOLYBDOVANADATE; SYSTEMS; SOLIDS;

D O I：

10.1039/c2cc17670j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled reductive assembly of capped Keggin anions [PMo12O40-(MLm)(n)](3-) has been achieved by reduction of [PMo12O40](3-) with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40{Co(MeCN)(2)}](3-) and bi-capped [PMo12O40(VO)(2)](3-) and [PMo12O40Sb2](3-)

引用

页码：2779 / 2781

页数：3

共 39 条

[1]

[Anonymous], 1998, COLLECT EVAL CCD

[2]

Artero V, 2000, EUR J INORG CHEM, P2393

[3] STRUCTURE OF A HETEROPOLY BLUE - THE 4-ELECTRON REDUCED BETA-12-MOLYBDOPHOSPHATE ANION [J].

BARROWS, JN ;

JAMESON, GB ;

POPE, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (06) :1771-1773

[4] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[5] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[6]

*BRUK AXS INC, 2008, APEX2 SADABS

[7] A bivanadyl capped, highly reduced Keggin polyanion, [PMo(V)(6)Mo(VI)(6)O(40)(V(IV)O)(2)](5-) [J].

Chen, Q ;

Hill, CL .

INORGANIC CHEMISTRY, 1996, 35 (08) :2403-&

[8]

DAMOUR H, 1976, Z KRISTALLOGR, V143, P1

[9]

Dolbecq A, 2005, EUR J INORG CHEM, P3009

[10] Hydrothermal syntheses:: A route to the stepwise condensation of reduced Keggin polyanions.: From reduced β-[HmSiMo12O40]n- monomers to bicapped dimerized [Si2Mo28O84(H2O)2]6- anions [J].

Dolbecq, A ;

Cadot, E ;

Eisner, D ;

Sécheresse, F .

INORGANIC CHEMISTRY, 1999, 38 (19) :4217-4223

← 1 2 3 4 →