Rational addition of capping groups to the phosphomolybdate Keggin anion [PMo12O40]3- by mild, non-aqueous reductive aggregation

被引：24

作者：

Bakri, Ridla ^{[1
]}

Booth, Andrew ^{[1
]}

Harle, Gavin ^{[1
]}

Middleton, Paul S. ^{[1
]}

Wills, Corinne ^{[1
]}

Clegg, William ^{[1
]}

Harrington, Ross W. ^{[1
]}

Errington, R. John ^{[1
]}

机构：

[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

BOND-VALENCE PARAMETERS; RAY CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESES; BUILDING-BLOCKS; FRAMEWORKS; POLYANION; CLUSTERS; MOLYBDOVANADATE; SYSTEMS; SOLIDS;

D O I：

10.1039/c2cc17670j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Controlled reductive assembly of capped Keggin anions [PMo12O40-(MLm)(n)](3-) has been achieved by reduction of [PMo12O40](3-) with sodium-mercury amalgam in the presence of metal halides, as exemplified by the rational syntheses of mono-capped [PMo12O40{Co(MeCN)(2)}](3-) and bi-capped [PMo12O40(VO)(2)](3-) and [PMo12O40Sb2](3-)

引用

页码：2779 / 2781

页数：3

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