Coherency strain effects on the optical response of core/shell heteronanostructures

被引:185
作者
Chen, XB [1 ]
Lou, YB [1 ]
Samia, AC [1 ]
Burda, C [1 ]
机构
[1] Case Western Reserve Univ, Dept Chem, Ctr Chem Dynam & Nanomat Res, Cleveland, OH 44106 USA
关键词
D O I
10.1021/nl034243b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Core/shell-structured CdSe/CdS nanoparticles were prepared by a one-pot procedure. The interface effect was studied by steady-state and time-resolved photoluminescence spectroscopy. Coherency strain across the CdSe/CdS interface is addressed to rationalize the measured optical response. The optical properties of the different core/shell systems agree with Matthews-Blakeslee theory, which predicts a critical thickness for a defect-free shell of less than two monolayers of capping material for the CdSe/CdS system.
引用
收藏
页码:799 / 803
页数:5
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