Responsive lanthanide luminescent cyclen complexes: from switching/sensing to supramolecular architectures

被引:279
作者
Gunnlaugsson, T [1 ]
Leonard, JP [1 ]
机构
[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland
关键词
D O I
10.1039/b418196d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article highlights some of the recent developments in the use of responsive cyclen based lanthanide luminescent devices, focusing on Eu(III), Tb(III), Nd(III) and Yb(III) complexes, where the photophysical properties, such as the excited state lifetimes, quantum yield/intensity and emission polarisation are modulated by the local chemical environment, e. g. ions and molecules, or through self-assembly of either f-f or mixed f-d cyclen complexes.
引用
收藏
页码:3114 / 3131
页数:18
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