An expeditious preparation of 15-membered nitrogen-containing olefinic and benzo macrocycles

被引:2
作者
Sebastián, RM [1 ]
Moreno-Mañas, M [1 ]
Vallribera, A [1 ]
机构
[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain
关键词
alkene ligands; heterocycles; macrocycles; silver;
D O I
10.1002/ejoc.200300171
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
(E,E)-1,6,11-Tris(arenesulfonyl)-3,4-benzo-1,6,11-triazacyclo-pentadeca-8,13-dienes (2) and 1,6,11-tris(arenesulfonyl)-3,4; 8,9;13,14-tribenzo-1,6,11-triazacyclopentadecanes (3) were prepared from arenesulfonamides, trans-1,4-dibromobutene, and 1,2-bis(bromomethyl)benzene. They form unstable complexes with silver tetrafluoroborate. (C) Wiley-VCH Verlag GmbH Co.
引用
收藏
页码:3382 / 3386
页数:5
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