Molecular design toward efficient polymer solar cells processed by green solvents

被引:41
作者
Chen, Yu [1 ,2 ]
Cui, Yong [1 ]
Zhang, Shaoqing [1 ]
Hou, Jianhui [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
关键词
IMPROVED PERFORMANCE; PHOTOVOLTAIC CELLS; PHASE-SEPARATION; ADDITIVES;
D O I
10.1039/c5py00431d
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel BDT-based conjugated polymer, PBDTTT-S-TEG, and a series of new fullerene derivatives were designed, synthesized and applied to green solvent processable polymer solar cells. By rationally screening processing solvents, a PCE of 4.50% was firstly achieved with definitely low toxic, non-halogenated and safe solvent fabrication, which is almost identical to that processed with o-dichlorobenzene.
引用
收藏
页码:4089 / 4095
页数:7
相关论文
共 27 条
[11]   Efficient Polymer Solar Cells Based on Poly(3-hexylthiophene) and Indene-C60 Bisadduct Fabricated with Non-halogenated Solvents [J].
Guo, Xia ;
Zhang, Maojie ;
Cui, Chaohua ;
Hou, Jianhui ;
Li, Yongfang .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (11) :8190-8198
[12]   25th Anniversary Article: Bulk Heterojunction Solar Cells: Understanding the Mechanism of Operation [J].
Heeger, Alan J. .
ADVANCED MATERIALS, 2014, 26 (01) :10-28
[13]   Improved Performance of Polymer Bulk Heterojunction Solar Cells Through the Reduction of Phase Separation via Solvent Additives [J].
Hoven, Corey V. ;
Dang, Xuan-Dung ;
Coffin, Robert C. ;
Peet, Jeff ;
Nguyen, Thuc-Quyen ;
Bazan, Guillermo C. .
ADVANCED MATERIALS, 2010, 22 (08) :E63-+
[14]   PREPARATION AND CHARACTERIZATION OF FULLEROID AND METHANOFULLERENE DERIVATIVES [J].
HUMMELEN, JC ;
KNIGHT, BW ;
LEPEQ, F ;
WUDL, F ;
YAO, J ;
WILKINS, CL .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) :532-538
[15]   Replacing Alkoxy Groups with Alkylthienyl Groups: A Feasible Approach To Improve the Properties of Photovoltaic Polymers [J].
Huo, Lijun ;
Zhang, Shaoqing ;
Guo, Xia ;
Xu, Feng ;
Li, Yongfang ;
Hou, Jianhui .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (41) :9697-9702
[16]  
Jailaubekov AE, 2013, NAT MATER, V12, P66, DOI [10.1038/NMAT3500, 10.1038/nmat3500]
[17]   Stability of Polymer Solar Cells [J].
Jorgensen, Mikkel ;
Norrman, Kion ;
Gevorgyan, Suren A. ;
Tromholt, Thomas ;
Andreasen, Birgitta ;
Krebs, Frederik C. .
ADVANCED MATERIALS, 2012, 24 (05) :580-612
[18]   Universal Correlation between Fibril Width and Quantum Efficiency in Diketopyrrolopyrrole-Based Polymer Solar Cells [J].
Li, Weiwei ;
Hendriks, Koen H. ;
Furlan, Alice ;
Roelofs, W. S. Christian ;
Wienk, Martijn M. ;
Janssen, Rene A. J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (50) :18942-18948
[19]   Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties [J].
Liang, Yongye ;
Feng, Danqin ;
Wu, Yue ;
Tsai, Szu-Ting ;
Li, Gang ;
Ray, Claire ;
Yu, Luping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7792-7799
[20]   Determination of the P3HT:PCBM solubility parameters via a binary solvent gradient method: Impact of solubility on the photovoltaic performance [J].
Machui, Florian ;
Langner, Stefan ;
Zhu, Xiangdong ;
Abbott, Steven ;
Brabec, Christoph J. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 100 :138-146