Solvent-free aziridination of α-nitroalkenes

被引：44

作者：

Fioravanti, S

Pellacani, L

Stabile, S

Tardella, PA

Ballini, R

机构：

[1] Univ La Sapienza, Dipartimento Chim, I-00185 Rome, Italy

[2] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy

来源：

TETRAHEDRON | 1998年 / 54卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(98)00309-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NsONHCO(2)Et in the presence of CaO reacts without solvent with alpha-nitroalkenes to give 1-(ethoxycarbonyl)-2-nitroaziridines (62-84%). a possible involvement of an aza-Michael route is proposed on the basis of regio- and stereochemical reaction outcome, compared also with the results of thermolysis of ethyl azidoformate on the same alpha-nitroalkenes. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：6169 / 6176

页数：8

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