Towards nanoprobes for conduction in molecular crystals: Dibenzoterrylene in anthracene crystals

被引:26
作者
Hofmann, C [1 ]
Nicolet, A [1 ]
Kol'chenko, MA [1 ]
Orrit, M [1 ]
机构
[1] Leiden Univ, MoNOs, Huygens Lab, NL-2333 CA Leiden, Netherlands
关键词
dibenzoterrylene; terrylene; naphthalene; anthracene; transistor; molecular crystal; FET-1 organic crystal; single molecule; nanoprobe;
D O I
10.1016/j.chemphys.2005.02.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The miniaturization of electronic devices and structures brings along the quest for instruments that operate on mesoscopic and nanometric scales. In these structures, nano-instruments could elucidate the rich variety of physical processes, an understanding of which will be necessary to develop and to predict the function of new nanoscale devices. For this purpose, we propose to use single molecules as nanoprobes and to address the probes individually by means of optical single molecule microscopy and spectroscopy. This would allow us to study the conduction in molecular crystals. Here, we compare different material systems and show that dibenzoterrylene in an anthracene crystal is a promising candidate system. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
相关论文
共 29 条
[1]   Mobility studies of field-effect transistor structures based on anthracene single crystals [J].
Aleshin, AN ;
Lee, JY ;
Chu, SW ;
Kim, JS ;
Park, YW .
APPLIED PHYSICS LETTERS, 2004, 84 (26) :5383-5385
[2]   DETECTION AND SPECTROSCOPY OF SINGLE PENTACENE MOLECULES IN A PARA-TERPHENYL CRYSTAL BY MEANS OF FLUORESCENCE EXCITATION [J].
AMBROSE, WP ;
BASCHE, T ;
MOERNER, WE .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (10) :7150-7163
[3]   Single molecule physics and chemistry [J].
Bai, CL ;
Wang, C ;
Xie, XS ;
Wolynes, PG .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (20) :11075-11076
[4]   Microscopic heterogeneities in the electrical properties of SiC as studied with single-molecule spectroscopy [J].
Bauer, A ;
Kador, L .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (51) :14301-14305
[5]   Electric-field effects of two-level systems observed with single-molecule spectroscopy [J].
Bauer, M ;
Kador, L .
JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (20) :9069-9072
[6]   Stark spectroscopy of single molecules in the Shpol'skii matrix n-hexadecane [J].
Bauer, M ;
Kador, L .
JOURNAL OF LUMINESCENCE, 2002, 98 (1-4) :75-79
[7]   Dibenzanthanthrene in n-hexadecane, dibenzoterrylene in naphthalene: Two new systems for single molecule spectroscopy [J].
Boiron, AM ;
Jelezko, F ;
Durand, Y ;
Lounis, B ;
Orrit, M .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 291 :41-44
[8]   The anomalous Stark effect of single terrylene molecules in p-terphenyl crystals [J].
Bordat, P ;
Orrit, M ;
Brown, R ;
Würger, A .
CHEMICAL PHYSICS, 2000, 258 (01) :63-72
[9]   Stark effect on single molecules of dibenzanthanthrene in a naphthalene crystal and in a n-hexadecane Shpol'skii matrix [J].
Brunel, C ;
Tamarat, P ;
Lounis, B ;
Woehl, JC ;
Orrit, M .
JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (14) :2429-2434
[10]   Probing local currents in semiconductors with single molecules [J].
Caruge, JM ;
Orrit, M .
PHYSICAL REVIEW B, 2001, 64 (20)