Formation of very weakly interacting organometallic cation-anion systems using Pearson's HSAB concept:: Synthesis and structures of [Ag(toluene)3]+ [{((SiMe3)3C)2Al2F5}2Li]- and [AlF2(THF)4]+ [{(SiMe3)3C}2Al2F5]-

被引：29

作者：

Hatop, H ^{[1
]}

Roesky, HW ^{[1
]}

Labahn, T ^{[1
]}

Ropken, C ^{[1
]}

Sheldrick, GM ^{[1
]}

Bhattacharjee, M ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 19期

关键词：

D O I：

10.1021/om9803016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using Pearson's HSAB principle [Ag(Toluene)(3)](+) [{((SiMe3)(3)C)(2)Al2F5}(2)Li](-) (2) has been synthesized from the reaction of [(SiMe3)(3)CalF(2)](3) (1) with AgF and LiCl. Reaction of 1 with AgF2 and NH4F affords [AlF2(THF)(4)](+) [{(SiMe3)(3)C}Al2F5](-) (3) and [NH4](+) [(SiMe3)(3)CalF(3)](-) (4), respectively. 2 and 3 have been structurally characterized.

引用

页码：4326 / 4328

页数：3

共 20 条

[1] SYNTHESIS OF BASE-FREE CATIONIC ZIRCONIUM METHYL AND BENZYL COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF (C5H3(SIME3)2-1,3)2ZRME(MU-ME)B(C6F5)3 [J].

BOCHMANN, M ;

LANCASTER, SJ ;

HURSTHOUSE, MB ;

MALIK, KMA .

ORGANOMETALLICS, 1994, 13 (06) :2235-2243

[2] LITHIUM BIS(DI-TERT-BUTYLFLUOROSILYL)PHOSPHIDE, A CYCLIC DIPOLAR ION [J].

KLINGEBIEL, U ;

MEYER, M ;

PIEPER, U ;

STALKE, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 408 (01) :19-25

[3] Synthesis and structures of paramagnetic organo titanium fluoride clusters [J].

Liu, FQ ;

Kunzel, A ;

Herzog, A ;

Roesky, HW ;

Noltemeyer, M ;

Fleischer, R ;

Stalke, D .

POLYHEDRON, 1997, 16 (01) :61-65

[4] (C(5)ME(5))TIF2 - A VERSATILE BUILDING-BLOCK FOR GENERATING LARGE SOLUBLE DIMETALLIC AGGREGATES [J].

LIU, FQ ;

STALKE, D ;

ROESKY, HW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1872-1874

[5] MOLECULAR-SOLIDS AS LIGANDS IN ORGANOMETALLIC CHEMISTRY - [CP(6)(ASTERISK)TI(6)NA(7)F(19)CENTER-DOT-2.5THF] (CP(ASTERISK)=C(5)ME(5)) AND [CP(4)(ASTERISK)TI(4)MG(2)F(12)CENTER-DOT-7THF], LINKS BETWEEN IONIC SOLIDS AND ORGANOMETALLIC COMPOUNDS [J].

LIU, FQ ;

KUHN, A ;

HERBSTIRMER, R ;

STALKE, D ;

ROESKY, HW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (05) :555-556

[6]

LIU FQ, 1994, ANGEW CHEM, V106, P577

[7]

LIU FQ, 1995, ANGEW CHEM, V107, P2004

[8] Organometallic fluorides: Compounds containing carbon-metal-fluorine fragments of d-block metals [J].

Murphy, EF ;

Murugavel, R ;

Roesky, HW .

CHEMICAL REVIEWS, 1997, 97 (08) :3425-3468

[9] ABSOLUTE ELECTRONEGATIVITY AND HARDNESS - APPLICATION TO INORGANIC-CHEMISTRY [J].

PEARSON, RG .

INORGANIC CHEMISTRY, 1988, 27 (04) :734-740

[10] HARD AND SOFT ACIDS AND BASES [J].

PEARSON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (22) :3533-&

← 1 2 →