Ternary Cu2SnS3 cabbage-like nanostructures: large-scale synthesis and their application in Li-ion batteries with superior reversible capacity

被引:85
作者
Qu, Baihua [1 ,2 ]
Li, Hongxing [1 ,2 ]
Zhang, Ming [1 ,2 ]
Mei, Lin [1 ,2 ]
Chen, Libao [1 ,2 ]
Wang, Yanguo [1 ,2 ,3 ]
Li, Qiuhong [1 ,2 ]
Wang, Taihong [1 ,2 ]
机构
[1] Hunan Univ, Key Lab Micronano Optoelect Devices, Minist Educ, Changsha 410082, Hunan, Peoples R China
[2] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[3] Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
RECHARGEABLE LITHIUM BATTERIES; HOLLOW NANOSPHERES; STORAGE CAPACITY; RATE CAPABILITY; ANODE MATERIALS; PERFORMANCE; ELECTRODES; CU; ARRAYS;
D O I
10.1039/c1nr10784d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, novel ternary Cu2SnS3 cabbage-like nanostructures are synthesized on a large scale via a facile solvothermal route. The individual Cu2SnS3 cabbage-like hierarchitecture is constructed from 2D nanosheets with thickness of about 15.6 nm. The Cu2SnS3 electrodes exhibit an initial reversible capacity of 842 mAh g(-1) and still reach 621 mAh g(-1) after 50 cycles. Such an admirable performance could be related to their 3D porous structural features as well as the high electrical conductivity induced by Cu. The electrochemical properties of the 3D hierarchical nanostructures imply its potential application in high energy density Li-ion batteries.
引用
收藏
页码:4389 / 4393
页数:5
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