Air stability of p-channel organic field-effect transistors based on oligo-p-phenylenevinylene derivatives

被引:17
作者
Ashimine, Tomoyuki [1 ]
Yasuda, Takeshi [1 ,2 ,3 ]
Saito, Masatoshi [4 ]
Nakamura, Hiroaki [4 ]
Tsutsui, Tetsuo [1 ,2 ]
机构
[1] Kyushu Univ, Grad Sch Engn Sci, Dept Appl Sci Elect & Mat, Fukuoka 8168580, Japan
[2] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan
[3] Japan Sci & Technol Agcy, PRESTO, Tokyo 1020075, Japan
[4] Idemitsu Kosan Co Ltd, Cent Res Labs, Sodegaura, Chiba 2990293, Japan
关键词
organic field-effect transistor; air stability; oligo-p-phenylenevinylene; organic semiconductor; highest occupied molecular orbital;
D O I
10.1143/JJAP.47.1760
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have investigated that the stability of organic field-effect transistors (OFETs) based on two oligo-p-phenylenevinylenes, 1,4-bis(4-methylstyryl)benzene (CH3-OPV) and 1,4-bis(4-dimethylaminostyryl)benzene [(CH3)(2)N-OPV], which is a new organic semiconductor for OFETs. The OFET fabricated using CH3-OPV with a highest occupied molecular orbital (HOMO) energy level of -5.55 eV shows good ambient stability even after storage in air for one year. On the other hand, the field-effect mobilities of organic semiconductors including (CH3)(2)N-OPV with the HOMO energy level ranging from -4.94 to -5.20 eV have decreased with time. The stability of CH3-OPV is suggested to be due to the relatively low HOMO energy level.
引用
收藏
页码:1760 / 1762
页数:3
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