The first structural characterization of α-zincated (Reformatsky) amides and phosphine oxides

被引：21

作者：

Hlavinka, ML ^{[1
]}

Hagadorn, JR ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 17期

关键词：

D O I：

10.1021/om050474c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The α-zincated derivatives of N,N-dimethylacetamide and trimethylphosphine oxide by H-Zn exchange with the organozinc precursor LZn 2Ph 2 were structurally characterized. The solid-state structure of LZn 2[CH 2P-(O)Me 2] 2 was determined by X-ray diffraction. The diasterotopic methylene (Zn-Ch 2-) was observed as a pair of upfield resonances at σ 0.80 and 0.03 ppm. The structural characterization of α-zincated derivatives show that the deprotonated amide and phosphine oxide molecules function as 1,3-bridging ligands between two Zn centers, both in solution and in the solid state.

引用

页码：4116 / 4118

页数：3

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