Development of shut-down process for a proton exchange membrane fuel cell

被引:34
作者
Kim, Hyoung-Juhn [1 ]
Lim, Sang Jin [1 ]
Lee, Jeung Woo [1 ]
Min, In-Gyu [1 ]
Lee, Sang-Yeop [1 ]
Cho, EunAe [1 ]
Oh, In-Hwan [1 ]
Lee, Jong Hyun [2 ]
Oh, Seung-Chan [2 ]
Lim, Tae-Won [2 ]
Lim, Tae-Hoon [1 ]
机构
[1] Korea Inst Sci & Technol, Fuel Cell Res Ctr, Seoul 136791, South Korea
[2] Hyundai Kia Corp Res & Dev Div, Fuel Cell Vehicle Team 1, Yongin 446912, Gyeonggi Do, South Korea
关键词
dummy load; membrane electrode assembly (MEA); polymer electrolyte membrane; proton exchange membrane fuel cell (PEMFC); shut-down process;
D O I
10.1016/j.jpowsour.2007.12.112
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Several different shut-down procedures were carried out to reduce the degradation of membrane electrode assembly (MEA) in a proton exchange membrane fuel cell (PEMFC). The effects of close/open state of outlets of a single cell and application of a dummy load during the shut-down on the degradation of the MEA were investigated. Also, we elucidated the relationship between the thickness of the electrolyte membrane and the degradation of the MEA for different shut-down procedures. When a thin electrolyte membrane was used, the closer of outlets mitigated the degradation during on/off operation. For the thicker electrolyte membrane, the dummy load which eliminates residual hydrogen and oxygen in the electrodes should be applied to lower the degradation. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:814 / 820
页数:7
相关论文
共 17 条
[1]   Formation process of nanocrystalline materials from x-ray diffraction profile analysis: Application to platinum catalysts [J].
Ascarelli, P ;
Contini, V ;
Giorgi, R .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (07) :4556-4561
[2]   PEM fuel cell Pt/C dissolution and deposition in nafion electrolyte [J].
Bi, Wu ;
Gray, Gary E. ;
Fuller, Thomas F. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (05) :B101-B104
[3]   PEM fuel cell electrocatalyst durability measurements [J].
Borup, Rod L. ;
Davey, John R. ;
Garzon, Fernando H. ;
Wood, David L. ;
Inbody, Michael A. .
JOURNAL OF POWER SOURCES, 2006, 163 (01) :76-81
[4]   Advanced materials for improved PEMFC performance and life [J].
Curtin, DE ;
Lousenberg, RD ;
Henry, TJ ;
Tangeman, PC ;
Tisack, ME .
JOURNAL OF POWER SOURCES, 2004, 131 (1-2) :41-48
[5]   Degradation study of MEA for PEMFCs under low humidity conditions [J].
Endoh, E ;
Terazono, S ;
Widjaja, H ;
Takimoto, Y .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (07) :A209-A211
[6]   Durability of perfluorinated ionomer membrane against hydrogen peroxide [J].
Kinumoto, Taro ;
Inaba, Minoru ;
Nakayama, Yoko ;
Ogata, Kazuhito ;
Umebayashi, Ryota ;
Tasaka, Akimasa ;
Iriyama, Yasutoshi ;
Abe, Takeshi ;
Ogumi, Zempachi .
JOURNAL OF POWER SOURCES, 2006, 158 (02) :1222-1228
[7]   Aging mechanisms and lifetime of PEFC and DMFC [J].
Knights, SD ;
Colbow, KM ;
St-Pierre, J ;
Wilkinson, DP .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :127-134
[8]   Durability study of proton exchange membrane fuel cells under dynamic testing conditions with cyclic current profile [J].
Liu, D. ;
Case, S. .
JOURNAL OF POWER SOURCES, 2006, 162 (01) :521-531
[9]   Effect of catalyst properties on membrane degradation rate and the underlying degradation mechanism in PEMFCs [J].
Mittal, Vishal O. ;
Kunz, H. Russell ;
Fenton, James M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (09) :A1755-A1759
[10]  
Perry ML, 2006, ECS Trans, V3, P783