Conjugate addition of alcohols to acrylic compounds catalyzed by a bifunctional ruthenium-acetamido complex

被引：34

作者：

Yi, CS ^{[1
]}

Yun, SY ^{[1
]}

He, ZJ ^{[1
]}

机构：

[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 15期

关键词：

D O I：

10.1021/om030418g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium-acetamido complex [(PCy3)(2)-(CO)(CH3CONH)(i-PrOH)RuH] (1) was found to be an effective catalyst for the conjugate addition of alcohols to acrylic compounds under mild reaction conditions to form beta-alkoxynitrile compounds. The bifunctional activity of 1 from the Lewis acid ruthenium center for facilitating N-coordination of acrylonitrile and the basic amido ligand for mediating heterolytic alcohol O-H bond cleavage have been proposed for the catalytic reaction.

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页码：3031 / 3033

页数：3

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