Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes

被引：66

作者：

Alnasleh, Bassam K. ^{[1
]}

Sherrill, William M. ^{[1
]}

Rubin, Michael ^{[1
]}

机构：

[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 15期

关键词：

D O I：

10.1021/ol8011138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel transition-metal-catalyzed addition of P-H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity.

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页码：3231 / 3234

页数：4

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