Silver(I)-catalyzed novel cascade cyclization reactions: Incorporation of allenes into the isochromenes

被引：64

作者：

Patil, NT ^{[1
]}

Pahadi, NK ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 24期

关键词：

D O I：

10.1021/jo051524q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The silver(I)-catalyzed reaction of alkynones with alcohols represents a general tool for the synthesis of 1-allenyl isochromenes. The reaction most probably proceeds via the formation of benzopyrylium cation, which subsequently undergoes nucleophilic attack of an alcohol to give the annulation products.

引用

页码：10096 / 10098

页数：3

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