Transylidation of a transiently formed nitrilium phosphane ylide complex

被引：31

作者：

Wilkens, H ^{[1
]}

Ruthe, F ^{[1
]}

Jones, PG ^{[1
]}

Streubel, R ^{[1
]}

机构：

[1] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a802569j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal decomposition of the 3-phenyl-substituted 2H-azaphosphirene complex 1 in the presence of dimethyl cyanamide and dimethyl acetylenedicarboxylate (DMAD) yielded dimethylamino-substituted products, the 2H-1,2-azaphosphole complex 4b and the diastereoisomeric Delta(3)-1,3,2-oxazaphospholene complexes 5a,b; this represents the first example of 1,3-dipolar cycloaddition reactions of a nitrilium phosphane ylide complex that is generated in situ by transylidation.

引用

页码：1529 / 1530

页数：2

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