Palladium-Catalyzed Tandem Diperoxidation/C-H Activation Resulting in Diperoxy-oxindole in Air

被引:53
作者
An, Guanghui [1 ]
Zhou, Wei [1 ]
Zhang, Guangqian [1 ]
Sun, Hao [1 ]
Han, Jianlin [1 ]
Pan, Yi [1 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
ALPHA-ARYLATION; MECHANISM; LIGAND; GAMMA;
D O I
10.1021/ol101664y
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A highly efficient and facile palladium-catalyzed tandem diperoxidation and C-H activation process was reported, which provides a new pathway for the synthesis of biologically active diperoxides as well as oxindole derivatives from readily available starting materials in excellent chemical yields
引用
收藏
页码:4482 / 4485
页数:4
相关论文
共 33 条
[31]   Synthesis of [59]fullerenones through peroxide-mediated stepwise cleavage of fullerene skeleton bonds and x-ray structures of their water-encapsulated open-cage complexes [J].
Xiao, Zuo ;
Yao, Jiayao ;
Yang, Dazhi ;
Wang, Fudong ;
Huang, Shaohua ;
Gan, Liangbing ;
Jia, Zhenshan ;
Jiang, Zhongping ;
Yang, Xiaobing ;
Zheng, Bo ;
Yuan, Gu ;
Zhang, Shiwei ;
Wang, Zheming .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :16149-16162
[32]   Organopalladium(IV) chemistry [J].
Xu, Ling-Min ;
Li, Bi-Jie ;
Yang, Zhen ;
Shi, Zhang-Jie .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (02) :712-733
[33]   Diverse pathways for the palladium(II)-mediated oxidation of olefins by tert-butylhydroperoxide [J].
Yu, JQ ;
Corey, EJ .
ORGANIC LETTERS, 2002, 4 (16) :2727-2730