Direct observation of polymer sheathing in carbon nanotube-polycarbonate composites

被引:208
作者
Ding, W
Eitan, A
Fisher, FT
Chen, X
Dikin, DA
Andrews, R
Brinson, LC
Schadler, LS
Ruoff, RS [1 ]
机构
[1] Northwestern Univ, Dept Mech Engn, Evanston, IL 60208 USA
[2] Rensselaer Polytech Inst, Troy, NY 12180 USA
[3] Univ Kentucky, Ctr Appl Energy Res, Lexington, KY 40511 USA
关键词
D O I
10.1021/nl0345973
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of observations of polymer sheathing in multiwalled carbon nanotube (MWCNT)-polycarbonate composites are presented. This sheathing was observed in images of the composite fracture surface and is consistent with diameter distributions of the as-received and embedded MWCNTs. A novel nanomanipulation experiment, where the sheathing balls up when contacted by an AFM tip, confirms this phenomenon. This sheathing layer is direct evidence of substantial MWCNT-polymer interaction and will influence the mechanical properties of MWCNT-polymer composites.
引用
收藏
页码:1593 / 1597
页数:5
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