Synthesis of nanocomposite organic/inorganic hybrid materials using controlled/"living" radical polymerization

被引:661
作者
Pyun, J [1 ]
Matyjaszewski, K [1 ]
机构
[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA
关键词
D O I
10.1021/cm011065j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The preparation of hybrid organic/inorganic nanocomposites comprised of well-defined polymers was reviewed. In particular, synthetic methods using controlled/"living" radical polymerization techniques, such as stable free-radical/nitroxide-mediated polymerizations, atom transfer radical polymerization, and reversible addition-fragmentation chain-transfer polymerization were described. The various approaches taken to prepare hybrid copolymers, nanoparticles, polymer brushes, dispersed silicate nanocomposites, and nanoporous materials were discussed.
引用
收藏
页码:3436 / 3448
页数:13
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