Synthesis of nanocomposite organic/inorganic hybrid materials using controlled/"living" radical polymerization

被引：661

作者：

Pyun, J ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 10期

关键词：

D O I：

10.1021/cm011065j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation of hybrid organic/inorganic nanocomposites comprised of well-defined polymers was reviewed. In particular, synthetic methods using controlled/"living" radical polymerization techniques, such as stable free-radical/nitroxide-mediated polymerizations, atom transfer radical polymerization, and reversible addition-fragmentation chain-transfer polymerization were described. The various approaches taken to prepare hybrid copolymers, nanoparticles, polymer brushes, dispersed silicate nanocomposites, and nanoporous materials were discussed.

引用

页码：3436 / 3448

页数：13

共 104 条

[81] Silsesquioxanes as synthetic platforms .3. Photocurable, liquid epoxides as inorganic/organic hybrid precursors [J].

Sellinger, A ;

Laine, RM .

CHEMISTRY OF MATERIALS, 1996, 8 (08) :1592-&

[82] Using atom transfer radical polymerization to amplify monolayers of initiators patterned by microcontact printing into polymer brushes for pattern transfer [J].

Shah, RR ;

Merreceyes, D ;

Husemann, M ;

Rees, I ;

Abbott, NL ;

Hawker, CJ ;

Hedrick, JL .

MACROMOLECULES, 2000, 33 (02) :597-605

[83] Improving the structural control of graft copolymers by combining ATRP with the macromonomer method [J].

Shinoda, H ;

Miller, PJ ;

Matyjaszewski, K .

MACROMOLECULES, 2001, 34 (10) :3186-3194

[84] CONTROLLED GROWTH OF MONODISPERSE SILICA SPHERES IN MICRON SIZE RANGE [J].

STOBER, W ;

FINK, A ;

BOHN, E .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1968, 26 (01) :62-&

[85] COMPOSITE OF COLLOIDAL CRYSTALS OF SILICA IN POLY(METHYL METHACRYLATE) [J].

SUNKARA, HB ;

JETHMALANI, JM ;

FORD, WT .

CHEMISTRY OF MATERIALS, 1994, 6 (04) :362-364

[86] EFFECT OF POLYMERIZATION CONDITIONS ON THE MOLECULAR-WEIGHT OF POLYSTYRENE GRAFTED ONTO SILICA IN THE RADICAL GRAFT-POLYMERIZATION INITIATED BY AZO OR PEROXYESTER GROUPS INTRODUCED ONTO THE SURFACE [J].

TSUBOKAWA, N ;

SHIRAI, Y ;

HASHIMOTO, K .

COLLOID AND POLYMER SCIENCE, 1995, 273 (11) :1049-1054

[87] Preparation of structurally well-defined polymer-nanoparticle hybrids with controlled/living radical polymerizations [J].

von Werne, T ;

Patten, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7409-7410

[88]

VONWERNE T, 2000, POLYM MAT SCI ENG, V82, P294

[89] Hybrid nanoparticles with block copolymer shell structures [J].

Watson, KJ ;

Zhu, J ;

Nguyen, ST ;

Mirkin, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (02) :462-463

[90] Direct synthesis of dispersed nanocomposites by in situ living free radical polymerization using a silicate-anchored initiator [J].

Weimer, MW ;

Chen, H ;

Giannelis, EP ;

Sogah, DY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (07) :1615-1616

← 2 3 4 5 6 7 8 9 10 11 →