Synthesis of nanocomposite organic/inorganic hybrid materials using controlled/"living" radical polymerization

被引：661

作者：

Pyun, J ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 10期

关键词：

D O I：

10.1021/cm011065j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation of hybrid organic/inorganic nanocomposites comprised of well-defined polymers was reviewed. In particular, synthetic methods using controlled/"living" radical polymerization techniques, such as stable free-radical/nitroxide-mediated polymerizations, atom transfer radical polymerization, and reversible addition-fragmentation chain-transfer polymerization were described. The various approaches taken to prepare hybrid copolymers, nanoparticles, polymer brushes, dispersed silicate nanocomposites, and nanoporous materials were discussed.

引用

页码：3436 / 3448

页数：13

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