Enantioselective allylic substitution using a novel (phosphino-1,3-oxazine)palladium catalyst

被引：55

作者：

Evans, PA

Brandt, TA

机构：

[1] Lammot du Pont Laboratory, Dept. of Chemistry and Biochemistry, University of Delaware, Newark

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(96)02162-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 1,3-diphenyl-2-propenylacetate 1 with the sodium salt of dimethyl malonate and the palladium complex of the phosphino-1,3-oxazine ligand cis-3a gave the allylic substitution product 2 in 99% yield and 95% enantiomeric excess. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：9143 / 9146

页数：4

共 25 条

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