Graphene oxide derived carbons (GODCs): synthesis and gas adsorption properties

被引:156
作者
Srinivas, Gadipelli [1 ,2 ]
Burress, Jacob [1 ]
Yildirim, Taner [1 ,2 ]
机构
[1] NIST, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
[2] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
关键词
METAL-ORGANIC FRAMEWORKS; ULTRAHIGH SURFACE-AREA; ACTIVATED CARBONS; ENHANCED HYDROGEN; METHANE STORAGE; GRAPHITE OXIDE; CO2; CAPTURE; PORE-SIZE; DIOXIDE; CAPACITY;
D O I
10.1039/c2ee21100a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis of a range of high surface area graphene oxide derived carbons (GODCs) and their applications toward carbon capture and methane storage. We obtain largely increased surface areas up to nearly 1900 m(2) g(-1) for GODC samples from 10 m(2) g(-1) of precursor graphene oxide (GO). Our GODCs reveal favourable gas adsorption capacities compared to other high surface area carbons. We show that producing high surface area carbons from GO precursor is a viable method, and the porosity parameters are easily tuneable for their potential gas adsorption applications.
引用
收藏
页码:6453 / 6459
页数:7
相关论文
共 51 条
[1]   Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].
Ben, Teng ;
Ren, Hao ;
Ma, Shengqian ;
Cao, Dapeng ;
Lan, Jianhui ;
Jing, Xiaofei ;
Wang, Wenchuan ;
Xu, Jun ;
Deng, Feng ;
Simmons, Jason M. ;
Qiu, Shilun ;
Zhu, Guangshan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460
[2]   Microporous carbon adsorbents with high CO2 capacities for industrial applications [J].
Builes, Santiago ;
Roussel, Thomas ;
Ghimbeu, Camelia Matei ;
Parmentier, Julien ;
Gadiou, Roger ;
Vix-Guterl, Cathie ;
Vega, Lourdes F. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (35) :16063-16070
[3]   Graphene Oxide Framework Materials: Theoretical Predictions and Experimental Results [J].
Burress, Jacob W. ;
Gadipelli, Srinivas ;
Ford, Jamie ;
Simmons, Jason M. ;
Zhou, Wei ;
Yildirim, Taner .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (47) :8902-8904
[4]   Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials [J].
Compton, Owen C. ;
Nguyen, SonBinh T. .
SMALL, 2010, 6 (06) :711-723
[5]   Pillared Graphene: A New 3-D Network Nanostructure for Enhanced Hydrogen Storage [J].
Dimitrakakis, Georgios K. ;
Tylianakis, Emmanuel ;
Froudakis, George E. .
NANO LETTERS, 2008, 8 (10) :3166-3170
[6]   Evaluation of Activated Carbon Adsorbents for CO2 Capture in Gasification [J].
Drage, Trevor C. ;
Blackman, James M. ;
Pevida, Cova ;
Snape, Colin E. .
ENERGY & FUELS, 2009, 23 (5-6) :2790-2796
[7]   Chemically Derived Graphene Oxide: Towards Large-Area Thin-Film Electronics and Optoelectronics [J].
Eda, Goki ;
Chhowalla, Manish .
ADVANCED MATERIALS, 2010, 22 (22) :2392-2415
[8]  
Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/NCHEM.834, 10.1038/nchem.834]
[9]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428
[10]   Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications [J].
Furukawa, Hiroyasu ;
Yaghi, Omar M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8875-8883