Molecular beam deposition of perylene on copper:: Formation of ordered phases

被引:19
作者
Söhnchen, S [1 ]
Hänel, K [1 ]
Birkner, A [1 ]
Witte, G [1 ]
Wöll, C [1 ]
机构
[1] Ruhr Univ Bochum, D-44780 Bochum, Germany
关键词
D O I
10.1021/cm051183x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The growth of ultrathin perylene films on Cu(110) and Cu(100) surfaces has been studied by means of He atom scattering, low-energy electron diffraction, scanning tunneling microscopy, thermal desorption spectroscopy, and X-ray photoelectron spectroscopy with a special emphasis on the interface structure. In addition to several ordered submonolayer phases, two distinctly different monolayer structures were found at substrate temperatures below 380 K and at about 450 K on Cu(110). The rather open saturation structure formed at elevated temperatures reveals an enhanced density of substrate steps, which indicates an adsorption-induced modification of the Cu(110) surface. In contrast to that, on Cu(100), only a close-packed c(8 x 4) monolayer structure is formed without any less-dense-packed structures.
引用
收藏
页码:5297 / 5304
页数:8
相关论文
共 29 条
[1]   Importance of dewetting in organic molecular-beam deposition:: Pentacene on gold [J].
Beernink, G ;
Strunskus, T ;
Witte, G ;
Wöll, C .
APPLIED PHYSICS LETTERS, 2004, 85 (03) :398-400
[2]   Surface facetting induced by adsorbates [J].
Chen, Q ;
Richardson, NV .
PROGRESS IN SURFACE SCIENCE, 2003, 73 (4-8) :59-77
[3]   Growth and evolution of perylene thin films on Cu(110) [J].
Chen, Q ;
McDowall, AJ ;
Richardson, NV .
CHEMISTRY OF MATERIALS, 2003, 15 (21) :4113-4117
[4]   Epitaxial growth of a crystalline organic semiconductor: Perylene/Cu{110} [J].
Chen, Q ;
Rada, T ;
McDowall, A ;
Richardson, NV .
CHEMISTRY OF MATERIALS, 2002, 14 (02) :743-749
[5]   Organic adsorbate induced surface reconstruction:: p-aminobenzoic acid on Cu{110} [J].
Chen, Q ;
Frankel, DJ ;
Richardson, NV .
LANGMUIR, 2001, 17 (26) :8276-8280
[6]   Electronic structure of the pentacene single crystal:: Relation to transport properties [J].
Cornil, J ;
Calbert, JP ;
Brédas, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (06) :1250-1251
[7]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[8]  
2-9
[9]   Metastable (2 3S) helium atom scattering from NiO(100) and Cu(100) surfaces [J].
Fouquet, P ;
Day, PK ;
Witte, G .
SURFACE SCIENCE, 1998, 400 (1-3) :140-154
[10]   Organic molecular-beam deposition of perylene on Cu(110):: Results from near-edge x-ray absorption spectroscopy, x-ray photoelectron spectroscopy, and atomic force microscopy [J].
Hänel, K ;
Söhnchen, S ;
Lukas, S ;
Beernink, G ;
Birkner, A ;
Strunskus, T ;
Witte, G ;
Wöll, C .
JOURNAL OF MATERIALS RESEARCH, 2004, 19 (07) :2049-2056