An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction

被引：1556

作者：

Fu, Yanghe ^{[1
]}

Sun, Dengrong ^{[1
]}

Chen, Yongjuan ^{[1
]}

Huang, Renkun ^{[1
]}

Ding, Zhengxin ^{[1
]}

Fu, Xianzhi ^{[1
]}

Li, Zhaohui ^{[1
]}

机构：

[1] Fuzhou Univ, State Key Lab Breeding Base, Res Inst Photocatalysis, Fujian Prov Key Lab Photocatalysis, Fuzhou 350002, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 14期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide; metal-organic frameworks; photocatalysis; reduction; CARBON-DIOXIDE; ROOM-TEMPERATURE; WATER; MOFS; BEHAVIOR; ACID;

D O I：

10.1002/anie.201108357

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Let your light shine: The photocatalytic reduction of carbon dioxide to the formate anion under visible light irradiation is for the first time realized over a photoactive Ti-containing metal-organic framework, NH 2-MIL- 125(Ti), which is fabricated by a facile substitution of ligands in the UV-responsive MIL-125(Ti) material (see scheme; TEOA=triethanolamine). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3364 / 3367

页数：4

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